01
Intrinsic viscosity (i.V.) and solid-state polymerization
i.V. is the viscosity of PET in dilute solution and indicates average chain length, that is, molecular weight; it is expressed in dL/g. Longer chains spread load across more points during stretching, which is why break strength and resistance to lengthwise splitting in an oriented strap depend on i.V. Solid-state polymerization (SSP) holds PET below its melting point under inert gas to continue polycondensation and raise i.V.; every melt-processing step, by contrast, tends to lower i.V. through moisture and heat. The solution viscosity of PET is measured with methods such as ISO 1628-5 and ASTM D4603.






